Start with the loads that move the bill
Most UK homes have a few loads that dominate the electricity bill: electric heating (for homes without gas), water heating, cooking, clothes drying, refrigeration, and EV charging. Unlike the US or Australia, UK homes typically use gas for space heating and hot water, so the electric load is lower but the gas bill is a parallel consideration. Small plug loads matter, but they usually do not decide solar sizing. A good energy estimate ranks electric loads by kWh first, then looks for behaviour, efficiency, or rate-plan changes.